Hsc Chemistry Notes: Conquering Chemistry

17746 Words71 Pages
Year 12 HSC Chemistry Notes (Conquering Chemistry) Module 1 – production of Materials Ethylene, polymers and ethanol * Fossil fuels – energy rich substances formed in the Earth’s crust under intense heat and pressure millions of years ago. Originally remains of marine organisms, they were converted into petroleum that is trapped near the Earth’s surface. Fossil fuels can be extracted and refined to provide energy, and the building blocks of crude oil can be used to create numerous materials for human use e.g. ethylene. * Petroleum – mixture of hydrocarbons, consists of liquid crude oil and gaseous natural petroleum gas. It can be separated using physical and chemical changes. Liquid crude oil can be separated in fractions via fractional…show more content…
Low density polyethylene (LDPE) – involves an older gas phase process (still used) with conditions: high pressure (1000-3000 times atmospheric), high temperature (300°C) and an initiator (an organic peroxide e.g. dibutyl peroxide, or oxygen). The resultant product has significant chain branching due to alkyl groups replacing hydrogen atoms on some carbon atoms. Consequently, the alkane chains cannot pack together in an orderly fashion, resulting in low densities and weak dispersion forces; therefore LDPE is soft, flexible and has a low melting point. The initiator isn’t strictly a catalyst as it is involved in the actual formation (one initiator molecule per ½ polymer molecule). LDPE is used in plastic bags, plastic bottles, and cling…show more content…
When glucose polymerises to become cellulose, water is eliminated and the structure becomes: The H and OH groups are omitted for clarity. It must noted that: for bonding to occur, alternate glucose units must be inverted as shown above; this bonding produces a very linear molecule due to the geometry of the rings and the C-O-C angles. * Biomass – material produced by living organisms, mainly it is plant material though it also includes animal excreta and algae material. Cellulose is the major component of plant biomass. * Cellulose as a source of chemicals – starch, another polymer of glucose, can be used as an alternative source for petrochemical products but there is more cellulose produced in plants than starch. Each glucose unit of cellulose has 6 carbons atoms joined together, a good starting point in making petrochemicals e.g. ethylene (2 C atoms). However, it is more difficult to break cellulose into glucose than starch due to the many hydrogen bonds in the long near-linear chains of cellulose forming compact fibres. There are two processes to break cellulose into

More about Hsc Chemistry Notes: Conquering Chemistry

Open Document