Chemical environment surrounding the carbons are different and therefore affecting the character of the hydrogens attached. This difference in chemical environment finally explains the different interaction between hydrogen and chlorine. Determination of percent yield, and relative reactivity data was processed after the products of the reaction were analyzed using Gas Chromatography. Percent yield was calculated for each isomer and determined to be; 5.94% for 1,1-dichlorobutane, 23.1% for 1,2-dichlorobutane, 47.1% for 1,3-dichlorobutane, and 23.9% for 1,4-dichlorobutane. The relative reactivity of the hydrogens H1, H2, H3 , and H4 were 0.37, 1.4, 2.9, and 1.0 respectively.
Separation of the components of Extra-Strength Excedrin I: Acid-Base extraction Introduction The purpose of this experiment is to analyze the purity of Extra-Strength Excedrin® by utilizing thin-layer chromatography and determine the percent recoveries of its components. Three active ingredients will be extracted and collected from two tablets of Extra-Strength Excedrin® by utilizing acid-base extraction method. Three active ingredients of Extra-Strength Excedrin® are acetylsalicylic acid(aspirin), acetaminophen and caffeine, and their structures are: In addition, there is a binding material, which binds other three components together. These compounds can be separated by acid-base extraction because of their different acidities. A binding material can be separated by dissolving the tablet in ether since three active ingredients are soluble.
Silver nitrate tested for 2o and 3o alkyl halides expected in dibromocholesterol and sulfuric acid tested for alkenes expected in cholesterol. Bromination had 68.8% yield, debromination 73.7% yield, and overall 53.3% of commercial cholesterol was recovered as synthesized cholesterol. For commercial cholesterol, dibromocholesterol, and synthesized cholesterol, melting points were 145.2-148.1oC, 109.0-110.1oC, 146.3-148.2oC and retention factor (Rf) values were 0.69, 0.80 respectively. Chemical tests confirmed expectations, though some alkenes were present in dibromocholesterol. The similar melting points of the synthesized product as compared to the literature value; and similar Rf values for commercial and synthesized cholesterol showed the purity of
Then you put the remaining liquid (neutral component mixture) through the suction filtration funnel to isolate the crystals. After 10-15 minutes, the crystals will be dry and you can weigh them and find their melting point. How is the neutral component of your 3-compound mixture isolated from the final methylene chloride solution? 16 of 22 4/16/12 9:15 PM StudyBlue Flashcard Printing of Lab Final 2211L UGA http://www.studyblue.com/servlet/printFlashcardDeck?deckId=... Name the four active ingredients that we will be testing for in the TLC of Analgesics lab: Ibuprophen Caffeine Acetaminophen Acetylsalicylic acid What solvent system will you be using to dissolve the common analgesics (power) in preparation for TLC spotting? Methylene chloride: ethanol (1:1 solution) What solvent system will you be using to "develop" your TLC plates in the TLC of Analgesics lab?
Fall 2011 Name_________________________ FDNS 4100 Exam 2 A 1. The activated form of biotin is ____. A. Biocytin B. Bisnorbiotin C. Biotinidase D. Biotinyladenylate E. Biotinyl peptides 2. Glucosidase is the enzyme at the brush border of the small intestinal cells responsible for dephosphorylating pyridoxal phosphate prior to digestion. A.
In the experiment, toluene was alkylated with 2-chloropropane to synthesize isomers of isopropyltoluene in 47% yield, weighing 2.66g. The final product had a purity of 91.8% while the appearance was a colourless clear liquid with a strong odour. The results suggest that although the product yield was low, the experimental design led to the production of isopropyltoluene in high purity. REFERENCES 1. Smith R, McKee J, Zanger M. The electrophilic bromination of toluene: Determination of the ortho, meta, and para ratios by quantitative FTIR spectrometry.
Samantha Monette Lab Section E Wednesday 10:00-12:50 p.m. Bromination/Debromination of Cholesterol Abstract: The purpose of this experiment was to purify commercial cholesterol. The commercial cholesterol was brominated using bromine as the reagent. After the compound was cooled and vacuum filtrated, dibromocholesterol was obtained. To purify the dibromocholesterol, zinc was added as the reagent. After a series of washes to remove any impurities, the compound was dried and decanted, cholesterol was synthesized.
Liquid-liquid extraction Informal report By: Afi Ahmed 100959296 Presented to: Devien Durbano CHM2203 May 26th 2014 Results and calculations Table 1: Mass of mixture containing benzoic acid, 2-naphthol, and hydroquinone dimethyl ether and recrystallization. Mass of mixture: 3.03g Compound | Original mass | Recrystallized mass | Benzoic Acid | 1.01 | 0.14 | 2-naphtol | 1.01 | 0.43 | Hydro. Dimethyl ether | 1.01 | 0.16 | With these values we are able to calculate the percent recovery for Benzoic acid, 2-napthol and the hydroquinone dimethyl ether. 1) Percent recovery for isolation of benzoic acid % Recovery = mass of recovered material _________________________________ x100% mass of starting material = (0.14/1.01) x100% = 13.86% That concludes that the percent recovery is 13.86%. 2) Percent recovery for isolation of benzoic acid % Recovery = mass of recovered material _________________________________ x100% mass of starting material = (0.43/1.01) x100% = 42.57% That concludes that the percent recovery is 42,57%.
Radu Purtuc | Chemistry 231 - Lab | Section 32 Ronnie :: team-member TECH 705, SEPARATING ACIDS AND NEUTRAL COMPOUNDS BY SOLVENT EXTRACTION - MACROSCALE EXTRACTION July 6, 2006 Lab Report INTRODUCTION Purpose: using extraction technique to separate acetanilide, p-toluic acid, and p-tert-butylphenol; then measure the melting points of each compound and comparing them to the statistical values. Background: separating acids and neutral compounds by solvent extraction is a useful technique used in practice by chemists to separate organic compounds from mixture of other compounds. It generally involve several steps, with limiting factors being the number and output purity of compounds to be extracted from source mixture. A number of specific compound solvents not inter-miscible are used to separate and dissolve compounds, and a physical transfer between solvents is employed. An example of use is cleaning compounds of impurities, where different solvents work as a molecular filter that interacts differentially with compound and impurities respectively.
2.1 Classes of Hydrocarbons: Aliphatic | Aromatic (aka Arenes) | Alkanes, Alkenes, Alkynes | Benzene is an example | Alkanes: All bonds are single bonds Alkenes: Contain at least one C-C double bond Alkynes: Contain at least one C-C triple bond 2.3 Bonding in H2: The Valence Bond Theory Sigma Bond: orbitals overlap along a line connecting the atoms 2.4 Bonding in H2: The Molecular Orbital Model Bonding Orbital and antibonding orbital produced 2.5: Introduction to Alkanes: Methane, Ethane and Propane Alkanes: CnH2n+2 2.6 sp3 Hybridization and Bonding in Methane Sp3 Hybridization 2.7 Bonding in Ethane CH3= Methyl Bonds with sigma bond 2.8 Isomeric Alkanes: The Butanes n-butane: four carbons are joined