e. is one-half. 3. The gas phase reaction A + B C has a reaction rate which is experimentally observed to follow the relationship rate = k[A]2[B]. Which one of the following would affect the value of the specific rate constant, k? a. decreasing the temperature b. changing the concentration of A c. changing the concentration of B d. changing the concentration of C e. letting the reaction go on for a long time 4.
At 225.0 °C a gas has a volume of 400.0 mL. What is the volume of this gas at 127.0 °C? Gay-Lussac ‘s Law: 1. Gives the relationship between pressure and temperature when volume and amount are held constant. If the temperature of a container is increased, the pressure increases.
18. Which graph shows the relationship between activation energy (Ea) and temperature? 19. Consider the following reaction: CH4(g) + 2O2(g) ( CO2(g) + 2H2O(g) At a certain temperature, 1.0 mol CH4 is consumed in 4.0 minutes. The rate of production of H2O is A.
2. Explain what relationship exists between the pressure and volume of a gas (assuming a constant temperature), based on your collected data. Answer: The relationship between Pressure and Volume is inversely proportional. As one decrease, the other increases. P1V1=P2V2 3.
Comparing the rate of appearance of C and the rate of disappearance of A, we get[pic]. A) [pic] B) [pic] C) [pic] D) [pic] E) [pic] Answer: A Diff: 1 Page Ref: Sec. 14.2 A flask is charged with 0.124 mol of A and allowed to react to form B according to the reaction A(g) →B(g). The following data are obtained for [A] as the reaction proceeds: [pic] 5) The average rate of disappearance of A between 10 s and 20 s is __________ mol/s. A) [pic] B) [pic] C) [pic] D) 454 E) [pic] Answer: A Diff: 1 Page Ref: Sec.
A) mesosphere B) tropopause C) thermosphere D) stratopause E) mesopause Answer: B Diff: 1 Page Ref: Sec. 18.1 5) The pressure of the atmosphere __________. A) increases with altitude B) follows the same trend as temperature C) decreases with altitude D) follows the reverse trend as temperature E) stays the same Answer: C Diff: 1 Page Ref: Sec. 18.1 6) [pic] What is the partial pressure or oxygen (in torr) in the atmosphere when the atmospheric pressure is 760.0 torr? A) 159 B) 430 C) 601 D) 720 E) 760 Answer: A Diff: 1 Page Ref: Sec.
The volume of a gas at constant pressure increases with the absolute temperature of the gas. The formula for Charles Law is V1/T1 = V2/T2. What would be the volume of a 2.0 L balloon at 25.0 Degrees C, which was placed in a container of ice water at 3.0 Degrees C? Formula- V1/T1 = V2/T2. V1=
Kpa | # of p. cc | 99.76 | 0 | 106.21 | 10 | 112.56 | 20 | 107.12 | -10 | 109.16 | 15 | 117.22 | 30 | pres. Kpa | temp C | 23.66 | 99.64 | 77.7 | 114.45 | 4 | 93 | Evaluation: (8 pts) Conclusion (Claim, evidence, warrant for each gas law) (15 pts) Yes there is a relationship between pressure and temperature. The graph shows the relationship. It shows that there is 0.2874 KPa for every one degree Celsius. The particles in the higher temperature move faster than when they are in a colder temperature.
1 can be re-written to derive the equation for the density of a gas, assuming ideal behavior: n = P Now multiply both sides by MW: n(MW) = P (MW) V RT V RT n(MW) is # moles x grams/mol = grams = mass, m Therefore: m = (P)(MW) = d , density (mass/volume, in grams/ liter ) (Eqn. 2) V RT where m = mass , in grams and MW = molecular weight, in grams/mole Therefore, at fixed P & T, the measurement of the mass of a vapor in a known volume will give the density of the vapor under those conditions. Since the MW and R are constant for a given gas, density measured at arbitrary experimental T, P conditions can be scaled to any desired T,P (usually STP, 273 K, 1 atm) by the following ratio: d1 T1 = d2 T2 (Eqn. 3) P1 P2 If P and T are also measured, the molecular weight of the substance can be determined by another easy algebraic re-arrangement of Eqn. 2: MW = m R T (Eqn.
i) How does the viscosity of a gas depend on pressure in the hard-sphere model? j) How does the average molecular speed scale with temperature? k) What is the maximum occupation number ni for Fermions? l) How does the heat capacity scale with temperature in the Debye model for low temperatures? m) How many optical phonon branches does a crystal with 4 atoms per unit cell have?