In the experiment, toluene was alkylated with 2-chloropropane to synthesize isomers of isopropyltoluene in 47% yield, weighing 2.66g. The final product had a purity of 91.8% while the appearance was a colourless clear liquid with a strong odour. The results suggest that although the product yield was low, the experimental design led to the production of isopropyltoluene in high purity. REFERENCES 1. Smith R, McKee J, Zanger M. The electrophilic bromination of toluene: Determination of the ortho, meta, and para ratios by quantitative FTIR spectrometry.
There will have some error. 2) A volatile liquid was allowed to evaporate in a 43.298 g flask that has a total volume of 252 ml. the temperature of the water bath was 100˚C at the atmospheric pressure of 776 torr. The mass of the flask and condensed vapor was 44.173 g. calculate the molar mass of the liquid. T = 273 + 100 = 373 V = 252 mL = 1 L / 1000 mL = 0.252 L P = 776 Torr R= 0.0821 mass of 44.173 - 43.298 g = 0.875g moles of gas = PV / RT = 776 x .252 / 62.363 x (273+100) =0.00841 moles molar mass = 0.875g / 0.00841 moles = 104.1 g/
The NMR spectrum does contain impurities including methanol (4.80 ppm), methyl oleate (5.40 ppm), CHCL3 (7.20 ppm), acetone (2.00 ppm), and water (1.60 ppm). The methyl oleate may be present due to incomplete reaction with hydrogen and the CHCL3 may be present due to the contamination of CDCL3 NMR solvent. Acetone was used as a cleaning agent on the apparatus before starting the experiment. The experimental NMR spectrum does match that of an authentic spectrum except the experimental spectrum contains a greater number of peaks due to
1 / [CO2] C. [CaO][CO2] / [CaCO3] D. [CaCO3] / [CaO][CO2] _____ 13. The value of Kp for the reaction 2 NO2 (g) [pic] N2O4 (g) is 1.52 at 319 K. What is the value of Kp at this temperature for the reaction N2O4 (g) [pic] 2 NO2 (g) ? A. -1.52 B. 1.23 C. 5.74 X 10-4 D. 0.658 _____ 14.
LabQuest 34 Vapor Pressure and Heat of Vaporization Vapor pressure or scientifically called equilibrium vapor pressure is the condition wherein the vapor from a liquid over the same liquid in a sealed container is at a point wherein the amount of gas leaving the liquid equals the amount of gas re-entering the liquid from the vapor above the liquid. However there is a mathematical between temperature and vapor pressure, and the Clausius-Clayperon equation attest to this relationship. Clausius-Clayperon equation - ln P = - [∆Hvap / R][1/T] +C The intent of this experiment was to determine the temperature/vapor pressure relationship using the volatile liquid ethanol, CH3CH2OH; and calculate its heat of vaporization. This data was collected over a range of temperatures, 22.4° C to 34.9° C. It was intentional that the temperature remained under 40° C less the pressure inside the Erlenmeyer flask got high enough to pop the stopper out of the Erlenmeyer flask. Materials and equipment: MATERIALS Labquest 20 mL syringe Labquest App two 125 mL Erlenmeyer flasks Vernier Gas Pressure Sensor ethanol, CH3CH2OH Temperature Probe 400 mL beaker rubber stopper assembly 1 liter beaker plastic tubing with two connectors hot plate Procedure: The apparatus was set up as requested by the Lab quest 34 handout and an initial pressure reading of 101.6kpa was obtained at room temperature, 22.4° C. Then the Erlenmeyer flask and the sensors were conditioned to the water bath by holding the flask down into the water bath to the bottom of the white stopper for 30 seconds, and then the valve on the white stopper was closed to keep the ethanol vapor from leaving the container at any time during the experiment.
2-propanol (bp=82 degrees C) 3. tetrahydofuran (bp=65 degrees C) 4. 1-butanol (bp=118 degrees C) 5. butanone (bp=80 degrees C) Give a better separation for the mixture to be distilled tetrahydofuran (bp=65 degrees C) because it is farthest from 100 degrees C Which alkyl halide would react fastest in a nucleophilic substitution using silver nitrate in ethanol (weak nucleophile, protic solvent)? 3-bromo-3-methylpentane (most
Next the freezing point which didn’t eliminate either of them. Next we look at the mass which was 7.465g/ml. This make me lean toward ethyl ether but the masses were still pretty close. Next we move to the solubility of the substances. They are both very soluble in alcohol and hexane so that doesn’t help, but in water ethyl ether is semi soluble and pentane is in soluble.
This table shows the data collected while standardizing NaOH. With finding the volume used/ final volume. Trials | Mass of KHPthl (g) | Initial volume (mL) | Final volume(mL) | Volume used(mL) | 1 | 1.02 | 0.00 | 36.10 | 36.10 | 2 | 1.01 | 0.00 | 38.5 | 38.5 | 3 | 1.00 | 0.00 | 39.1 | 39.1 | Potassium hydrogen phthalate is used for standardizing NaOH because it is slightly acidic, which is often used with NaOH and is used as a buffering
(4.) What is the total pressure(mmHg) of a gas mixture containing argon gas at 0.25 atm, helium gas at 350 mmHg and nitrogen gas at 360 torr. (Hint: use Dalton’s Law of Partial Pressures). *Dalton’s Law: a gas law stating that the total pressure exerted by a mixture of gases in a container is the sum of the partial pressures that each gas would exert alone. *Partial Pressure: the pressure exerted by a single gas in a gas mixture.
This is because when an azeotrope is boiled, the resulting vapour has the same ratio of constituents as the original mixture of liquids. Each azeotrope has a characteristic boiling point. The boiling point of an azeotrope is either less than the boiling points of any of its constituents (a positive azeotrope), or greater than the boiling point of any of its constituents (a negative azeotrope). The azeotropes of cyclohexanol/water and cyclohexene/water are both positive azeotropes. The separation of cyclohexene could not depend on distillation alone.