Metal Complex Essay

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The stoichiometries of nickel-ethylenediamine complexes are determined by visible absorption spectra at room temperature and atmospheric pressure. Titration was used to make the different ration of NiSO4 and ethylenediamine. Then the absorbance of each ratio mixture was found. The mole fraction found in this experiment was .533 with wavelength of 605 nm. This value is compared to the 0.6 given. The major source of error could be that the burette is not completely clean and dry. Background: Metal complexes are what transitional metal ion form when they are in aqueous solution and are paired with cation. Chitosan is method of metal complexes that binds to nitrogen. In agriculture, this process is used as an anti-fungal in plants. It is not that harmful to mammals, for all the compounds are from natural sources on earth. The process starts by mixing chitin with a transition metal forming the complexes. They then spray on the leaves of affected areas and the fungi is poisoned. The plant itself is not affected. Table 1. Corrected wavelength Table 1. Corrected wavelength Procedure: Hirko,R. Chemistry 114L General Chemistry II Laboratory , Seventh Edition; bluedoor: Minnetonka, MN, 2013 ; Experiment 21 Results: Table 1 can be determined by equation 1 which determines the corrected absorbance at a given wavelength. Figure 1 shows the en of certain ratio at room temperatures. Figure 2 shows the absorbance versus en at 605 nm. Figure 3 shows the corrected absorbance at wavelengths 500 to 700 nm and used equation 2. 1. Yƛ=Aƛ-(1-Xen)Nƛ 2. Xen/(1-Xen) | ƛ=605 | ƛ=550 | Mole fraction en | Y605 | Y550 |

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