Molar Solubility Lab Report

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1a) Calculate molar solubility of SrF2 in: 0.010 M Sr(NO3)2 SrF2 <=> Sr+2 & 2 F- Ksp = [Sr+2] [F-]^2 4.3x10^-9 = [0.010 M] [F-]^2 [F-]^2 = (4.3x10^-9) / [0.010 M] [F-]^2 = 4.3x10^-7 [F-] = 6.56 X 10^-4 Molar by the equation: 1 mole of SrF2 <=> Sr+2 & 2 moles of F- the molar solubility of SrF2 that releases [F-] is half as much: 3.279 X 10^-4 Molar SrF2 yoiur answer, rounded to 2 sig figs would be 3.3 X 10^-4 Molar SrF2 ======================================… 1b) Calculate molar solubility of SrF2(Ksp=4.3x10^-9) in 0.010 M NaF Ksp = [Sr+2] [F-]^2 4.3x10^-9 = [Sr+2] [0.010]^2 [Sr+2] = 4.3x10^-9 / [0.010]^2 [Sr+2] = 4.3x10^-9 / 1 X 10^-4 [Sr+2] = 4.3x10^-5 Molar by the equation:…show more content…
Kf for (Ag(CN)2-) is 3.0x10^20 ; Ksp for Agl is 8.5x10^-17 Agl <=> Ag+ & I- Ksp = [ Ag+] [I-] Ag+ & 2 CN- <=> [Ag(CN)2]- Kf = [Ag(CN)2]- / [Ag+] [CN-…show more content…
0.10 M NaCN can only combine with 1/2 as many Ag+'s when it makes (Ag(CN)2-) so, yoiur answer is really 0.05 molar solubility of Agl in 0.10 M NaCN ======================================… 3) Predict whether solubility of BaF2 will increase, decrease, or remain the same with the addition of: a) HCl adds H+ , which removes F- ion, by converting it into HF the equilib: BaF2 <=> Ba+2 & 2F- will shift to the right to replace lost F- so,solubility of BaF2 will increase b) KF adds F-, which increases the F- ion, the equilib: BaF2 <=> Ba+2 & 2F- will shift to the left to reduce the added F- so,solubility of BaF2 will decrease c) NaNO3 solubility of BaF2 will remain the same, Na+ions & NO3-1 ions are not in the equilibrium ... and they do not combine with, to remove either Ba+2 ions or F- ions d) Ba(NO3)2 adds Ba+2, which increases the Ba+2 ion concentration, the equilib: BaF2 <=> Ba+2 & 2F- will shift to the left to reduce the added

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