2608T_ch19sm_S223-S237 02/22/2008 2:47 pm Page 223 pinnacle 111:WHQY028:Solutions Manual:Ch-19: Oxidative Phosphorylation and Photophosphorylation chapter 19 2H 1. Oxidation-Reduction Reactions The NADH dehydrogenase complex of the mitochondrial respiratory chain promotes the following series of oxidation-reduction reactions, in which Fe3 and Fe2 represent the iron in iron-sulfur centers, Q is ubiquinone, QH2 is ubiquinol, and E is the enzyme: (1) NADH 2 H E-FMN 88n NAD 2Fe 3 E-FMNH2 2Fe2 (2) E-FMNH2 (3) 2Fe 2H H 88n E-FMN 3 Q 88n 2Fe QH2 QH2 Sum: NADH Q 88n NAD For each of the three reactions catalyzed by the NADH dehydrogenase complex, identify (a) the electron donor, (b) the electron
Introduction: The radical chlorination of chlorobutane results in the formation of four possible products. These products are formed by substitution reactions, where a halogen atom (chlorine) replaces a hydrogen atom (Wade 2010). The amount of each product formed is based on the relative reactivity of the product. The calculations of the relative reactivity are dependent on the reactivity of the hydrogen atoms, which is influenced by the chloro substituent as well as other factors such as the level of the substituted carbon and the bond dissociation energy. For this lab we want to observe how the chloro substituent has an effect on the reactivity of the possible hydrogen atoms.
2 marks 4 Draw the structural formula of Compound G. 1 mark 5 Using the chemical shift correlation for 13C NMR, predict the number of peaks for Compound G and draw in the position of the peaks on the blank spectrum below, annotating each peak with its corresponding structure. (2 marks) 6 Draw the structural formula for 2-chloro but-2-ene. Below this draw a structural formula of an isomer of 2-chloro but-2-ene and name this substance.
Chlorine gas can be produced in the laboratory by adding concentrated hydrochloric acid to manganese(IV) oxide in the following reaction: MnO2(s) + 4HCl(aq) ( MnCl2(aq) + 2H2O(l) + Cl2(g) a. Calculate the mass of MnO2 needed to produce 25.0 g Of Cl2 ans: 30.7 g MnO2 b. What mass of MnCl2 is produced when 0.091 g of C12 is generated? ans: 0.16 g MnCl2 1. How many moles of ammonium sulfate can be made from the reaction of 30.0 mol of NH3 with H2SO4 according to the following equation: ans.
With which instrument will we measure the amount of product formed by the enzymatic reactions? (1 point) b. What property must a substance have in order to be measured by the instrument in part (a)? (1 point) c. What is the measurable product of each enzyme reaction? (2 points) 13.
Question 1 Answers: The sum of all chemical reactions is referred as metabolism. This is divided into catabolism in which complex substances are broken down into simple ones, with the release of ATP, and anabolism in which simple substances are used to make complex ones, spending energy. This type of reaction is also known as a biosynthetic reaction. Part of the energy in both types of reactions is lost to the environment as heat, metabolic pathways are defined as the sequences of chemical reactions in the cell. All these reactions result from the action of specialized proteins known as enzymes.
Once this molecules binds in the Krebs cycle it forms tricarboxylic acid and citric acid. When the coenzymes bind it enter into the electron system. While there ATP is then released as energy throughout the body. B. Compare three features of saturated and unsaturated fatty acids.
MULTIPLE CHOICE: Choose the most appropriate answer and enter it on the answer sheet 1. The formation of a peptide bond between two amino acids is an example of a(n) ______________ reaction. A) cleavage B) condensation C) group transfer D) isomerization E) oxidation reduction 2. Which of the following statements about cystine is correct? A) Cystine forms when the —CH2—SH R group is oxidized to form a —CH2—S—S—CH2— disulfide bridge between two cysteines.
Human Physiology: An Integrated Approach, 6e (Silverthorn) Chapter 2 Molecular Interactions 1) Stanley Miller set out to demonstrate an explanation for the origins of organic molecules using a combination of simple organic molecules, heat and periodic burst of electricity through the mixture, ultimately producing what kind of molecules? A) carbohydrates B) amino acids C) lipids D) glycoproteins E) nucleic acids Answer: B Section Title: Molecules and Bonds Learning Outcome: 2.1 Skill: Level I: Reviewing Facts and Terms (Bloom's Taxonomy: Comprehension) 2) Glycosylated molecules are those formed with which group of organic compounds? A) lipids B) nucleic acids C) proteins D) carbohydrates E) lipoproteins Answer: D Section Title: Molecules and Bonds Learning Outcome: 2.1 Skill: Level I: Reviewing Facts and Terms (Bloom's Taxonomy: Knowledge) 3) Cells regulate their level of activity by regulating the amount of proteins present in the cell at any given time, so an up regulation of enzymes would be expected to A) increase the level of productivity of chemical reactions that rely on them. B) decrease the level of productivity of chemical reactions that rely on them. C) increase the rate of reactions catalyzed by the enzymes.
Contents Chapter 1 Chapter 2 Chapter 3 Chapter 4 Chapter 5 Chapter 6 Chapter 7 Chapter 8 Chapter 9 Chapter 10 Chapter 11 Chapter 12 Chapter 13 Chapter 14 Chapter 15 Chapter 16 Chapter 17 Chapter 18 Chapter 19 Chapter 20 Chapter 21 Chapter 22 Chapter 23 Introduction to Biochemistry Water Amino Acids and the Primary Structures of Proteins Proteins: Three-Dimensional Structure and Function Properties of Enzymes Mechanisms of Enzymes Coenzymes and Vitamins Carbohydrates Lipids and Membranes Introduction to Metabolism Glycolysis Gluconeogenesis, The Pentose Phosphate Pathway, and Glycogen Metabolism The Citric Acid Cycle Electron Transport and Oxidative Phosphorylation Photosynthesis Lipid Metabolism Amino