Reaction Of Carboxylic Acids

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Summary of Principles Chemiluminescence is the emission of light during a chemical reaction. The purpose of this experiment is to show the principle of chemiluminescence when luminol is oxidized by hydrogen peroxide. Energy released in this reaction causes excitation of electrons when the excited electrons return to their ground state, visible light is emitted Pre-Lab Questions 1. Not Applicable 2. Not Applicable 3. What is luminescence? Luminescence is a way of producing light without giving out heat. Electrons inside the atoms of the luminescent material produce the light. Electrons gain energy by absorbing light, or electrical energy but not heat. They then give out light as they lose that energy. It is emission of light by a substance not resulting from heat; it is thus a form of cold body radiation. It can be caused by chemical reactions, electrical energy or subatomic motions. This distinguishes luminescence from incandescence, which is light emitted by a substance as a result of heating. Luminescence is useful in situations where the presence of heat would potentially be dangerous. For example, in televisions, there are dyes on the inside surface of a television screen called phosphors. These can give out light without being hot. If they did give out heat, the television would quickly become a fire risk Equation and Mechanism Apparatus and Supplies Test tubes, 1L Erlenmeyer flask, Funnel, water, Beakers, Measuring Cylinders. Chemicals Luminol Sodium Hydroxide Potassium Ferricyanide Hydrogen Peroxide Outline of Experimental Procedure 1. Solution A: Carefully dissolve 0.2g luminol in 10 ml of 10% aqueous sodium hydroxide and add 90 ml of water. 2. Solution B: Mix 20 ml of 3% aqueous Potassium Ferricyanide, 20 ml of 3% Hydrogen Peroxide and 160 ml of water. 3. Dilute 25 ml of solution A with 175ml of water in a dark area of

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