Objectives: The purpose of this lab is to observe the reaction of crystal violet and sodium hydroxide by looking at the relationship between concentration and time elapsed of the crystal violet. CV+ + OH- CVOH To quantitatively observe this reaction of crystal violet, the rate law is used. The rate law tells us that the rate is equal to a rate constant (k) multiplied by the concentration of crystal violet to the power of its reaction order ([CV+]p) and the concentration of hydroxide to the power of its reaction order ([OH-]q). Rate = k[CV+]p[OH-]q To fully understand the rate law, concentrations of the substances must be looked at first. The concentration is measured in molarity.
Use a calorimeter to measure the temperature change in each of three reactions. Calculate the heat of reaction, ∆H, for the three reactions. Use the results to confirm Hess’s law. Ev al Figure 1 ua tio Na+(aq) + OH–(aq) + H+(aq) ) + Cl–(aq) → H2O(l) + Na+(aq) + Cl–(aq) ∆H3 = ? n (3) Solutions of aqueous sodium hydroxide and hydrochloric acid react to form water and aqueous sodium chloride.
The purpose of the lab was to determine which reactant was the limiting reactant, and to see how much of the other reactant was used. The true molarity of a compound can be defined as the amount of moles per liter of that substance. The equation of this single displacement chemical reaction done during this lab is 2Al(s) + 3CuCl(aq) → 3Cu (s) + 2AlCl2 (aq). In the reaction, the solid Aluminum replaces the Copper in Copper (II) Chloride to produce solid copper, and Aluminum Chloride. In order to find which reactant is the limiting reactant, an equation based on the molarity of the Copper (II) Chloride may be used, or the products of the reaction may be observed.
I. Introduction Calorimetry is a used to determine the amount of heat transfer in a chemical reaction. It can measure one of two things: the amount of heat that is absorbed (in an endothermic process) or the amount that is gained (in an exothermic process). To conclude the calorimetry of a substance, the equation below is used: Eq. 1 q= Cs x g x T Q represents heat.
2 marks 4 Draw the structural formula of Compound G. 1 mark 5 Using the chemical shift correlation for 13C NMR, predict the number of peaks for Compound G and draw in the position of the peaks on the blank spectrum below, annotating each peak with its corresponding structure. (2 marks) 6 Draw the structural formula for 2-chloro but-2-ene. Below this draw a structural formula of an isomer of 2-chloro but-2-ene and name this substance.
NaOH (aq) + KHP (aq) —› Na+ (aq) + K + (aq) + P2- (aq) + H2O (l) NaOH (aq) + CH3COOH (aq) —› Na+ (aq) + CH3COO- (aq) + H2O (l) The titration of NaOH with KHP will identify the concentration of the NaOH provided. KHP will be weighed and its mass will be recorded. The moles of KHP will be calculated: Moles KHP = Mass KHP recorded / Molar mass of KHP = Mass of KHP recorded / 204.22g/mol The volume of NaOH will be determined by reading the
The Ksp of Magnesium Oxalate Abstract The Ksp for the acid catalyzed titration of the saturated oxalate is 1.8 x 10-3. Introduction In this experiment, the solubility equilibrium for the salt magnesium oxalate must be found in order to determine a solubility product constant. Solubility equilibrium is a type of dynamic equilibrium which exists when a chemical compound in the solid state is in chemical equilibrium with a solution of that compound. At the point of equilibrium the solution becomes saturated. The chemical reaction used to find this constant is as follows: MgC2O4 (s) ↔Mg(aq)2++ C2O4 (aq)2- Kc= Mg2+[C2O42-][MgC2O4] Ksp=Mg2+[C2O42-] The solid salt magnesium oxalate is prepared through the following precipitation reaction: Mg(SO4)(aq)+NaC2O4 (aq) → MgC2O4 (s)+NaSO4 (aq) Next, the concentration of the Mg2+ and C2O42- ions is found through a redox titration.
Using the G° data in your Appendix B, calculate the change in Gibbs free energy for each of the following reactions. In each case, indicate whether the reaction is spontaneous under standard conditions. a) H2 (g) + Cl2 (g) → 2HCl (g) b) MgCl2 (s) + H2O (l) → MgO (s) + 2 HCl (g) c) 2 NH3 (g) → N2H4 (g) + H2 (g) d) 2 NOCl (g) → 2 NO (g) + Cl2 (g) 4. From the values given for ΔH° and ΔS°, calculate ΔG° at 25°C for each of the following reactions. If the reaction is not spontaneous under standard conditions at 298K, at what temperature (if any) would the reaction become spontaneous?
EXPERIMENT 6 Title Kinetics of Chemical Reaction – Iodination of Cyclohexanone Aim To determine the value of the rate constant, k and order of reaction, a, b and c, and also to suggest a mechanism which agrees with the rate equation that has been obtained. Background Theory The basis of the theory of absorbance is as follows: Io ―――――→ sample ―――――→I if Io = I, no absorbance occur Io > I, the sample absorbs certain amount of light wave Io < I, the sample emits certain amount of light of certain wave length. THE HALOGENATION (IODINATION) OF KETONES (CYCLOHEXANONE) This experiment examined the rate of iodination of cyclohexanone in an aqueous medium. To increase the amount of iodine in the solution, iodine is converted to a more soluble complex ion, I3- by the addition of excess iodide ion: I2 + I- →I3- One of the characteristic reactions of ketones is the substitution of a halogen for one of the hydrogen is adjacent to the ketone group. The net reaction is: This reaction has been studied extensively and occurs for a wide variety of ketones.
How many moles of Al2O3 are produced by the reaction 200. g Al? 4Al + 302 → 2Al2O3 3.70 mole 12. How many moles Al are required to produce 300. g Al2O3? 4Al + 302 → 2Al2O3 5.88 mole 13. 100. g Al reacts with excess O2 to produce 150. g Al2O3 according to Calculate the theoretical and percentage yield.