Photocatalysis Hydrogen Essay

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Optimization of the co-catalyst in a carbon nitride based photocatalyst for the hydrogen generation Kyoung-Min Fündling Technical University of Berlin, Department of Chemistry Abstract The rising demand on energy and depletion of fossil energy resources has become a growing problem in the modern society and for the future. For these reasons hydrogen is considered and discussed as alternative energy source and gains its importance. Hydrogen has a high energy density and sets in the combustion exclusively energy and water free. Apart from gaining hydrogen from water in an electrolytic process, the photocatalytic water splitting with sunlight is a promising method to generate hydrogen. It is a well-known fact that the overall water splitting with a single catalyst is not the suitable way because of is low activity and high costs. Therefore the application of co-catalyst is a necessary for successful for photocatalytic hydrogen production. The concentrate on of co-catalyst and right method to deposit the nanoparticle on the surface of the photocatalyst can increase its activity. In this thesis a metal free carbon nitride is used as the photocatalyst, platinum as co-catalyst and triethanolamine as electron donor. [1] The in situ method is mostly used for enhancement of photocatalytic activity. A new method with the ex situ co-catalyst deposition with microemulsions and the cost effectiveness as comparison to the in situ process are investigated. The ex situ method “thermo-destabilization of microemulsions” uses microemulsions as the medium to synthesize platinum nanoparticle due to the simple control of the size and shape of the nanoparticles [2]. Platinum as co-catalyst was deposited in the microemulsions on the surface of the photocatalysts and almost without agglomeration. After deposition of the nanoparticles the photocatalytic activities of the photocatalyst were

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