Organic Melting Points

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The melting point of a substance is the temperature at which the material changes from a solid to a liquid state. The melting point is defined as the temperature at which the solid is in equilibrium with its liquid form. This characteristic is very unique and enables a substance to be determined by the melting point. Determination of the melting point is very important technique in many areas of organic chemistry because the melting point is really significant in order to identify the purity and the identity of a substance. Pure crystalline substances have a clear, defined melting point. However, impurities will distort this melting point and make it more difficult to define. During the melting process, all of the energy added to a substance is consumed as heat of fusion, and the temperature will remain constant. A pure substance will melt at a precisely defined temperature dependent solely on pressure. The pressure is generally assumed to be atmospheric pressure. This is a characteristic that is common to all crystalline substances. Determining the melting point of an organic is a straightforward method. However, as before, impurities can and will change the melting point of any given substance. Melting points are often used to characterize organic compounds in order to ascertain their purity. The melting point of a pure solid organic compound is one of its characteristic physical properties, along with molecular weight, boiling point, and density. Melting points are determined for several reasons. If the compound is a known, then the melting point will help to characterize the sample in hand. The range of the melting point is indicative of the purity of the compound; a pure solid will melt reproducibly over a narrow range of temperatures, less than 1 °C and an impure compound will melt over a wide range of temperatures. Recrystallization of the
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