Gen Chem 2 Practice Exam 2

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ID: A CHEM 1120, Dr. Gellert Mezei, Spring 2014, Practice Exam 2 Multiple Choice Identify the choice that best completes the statement or answers the question. Zero order: rate = k; [A] = [A]0 - akt; t1/2 = [A]0/2ak; First order: rate = k[A]; ln([A]0/[A]) = akt; t1/2 = ln2/ak; Second order: rate = k[A]2; 1/[A] - 1/[A]0 = akt; t1/2 = 1/ak[A]0 ____ 1. Which of the following statements about reaction orders in the rate law expression is incorrect? a. Their values may equal the stoichiometric coefficients in the balanced equation. b. Their values may or may not equal the stoichiometric coefficients in the balanced equation. c. Their values must be experimentally determined. d. Their values get larger as the temperature is increased. e. An order equal to zero means there is no concentration dependence with rate. 2. The gas phase reaction A + B  C has a reaction rate which is experimentally observed to follow the relationship rate = k[A]2[B]. The overall order of the reaction a. is first. b. is second. c. is third. d. is zero. e. is one-half. 3. The gas phase reaction A + B  C has a reaction rate which is experimentally observed to follow the relationship rate = k[A]2[B]. Which one of the following would affect the value of the specific rate constant, k? a. decreasing the temperature b. changing the concentration of A c. changing the concentration of B d. changing the concentration of C e. letting the reaction go on for a long time 4. The gas phase reaction A + B  C has a reaction rate which is experimentally observed to follow the relationship rate = k[A]2[B]. If the concentration of A is tripled and the concentration of B is doubled, the reaction rate would be increased by a factor of ____. a. 6 b. 9 c. 12 d. 18 e. 36 ____ ____ ____ 1 ID: A ____ 5. NO reacts with chlorine in a gas phase reaction to form nitrosyl chloride, NOCl. From the following

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