Chem Lab: Kinetics at Times Square

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Kinetics at Times Square Kinetics at Times Square Part 1: Focus Question: 1. As the concentration of acid increased the rate of which the magnesium was consumed also increased. 2. The linear plot determines the rate laws and so the rate law is Rate=k[HCl]2 Results Table: Mass of Mg (g) | HCl concentration (M) | Time (s) | Rate (g/s)(Grams of Mg/seconds) | HCl concentration 2 (M) | 0.0198 | 2 | 17 | 0.0198/17= 0.001164706 | 4 | 0.0198 | 1.5 | 30.73 | 0.0198/30.73= 0.000644322 | 2.25 | 0.0198 | 1 | 70.28 | 0.0198/70.28= 0.00028173 | 1 | 0.0198 | 0.75 | 127.8 | 0.0198/127.8= 0.00015493 | 0.5625 | 0.0198 | 0.5 | 292.43 | 0.0198/292.43= 6.77085E-05 | 0.25 | Kinetics at Times Square Part 2: Focus Question: 1. Rate= k[HSO3-]x[IO3-]y = 0.0005sec-1[HSO3-]1[IO3-]1 Table 2: Time per experiment Experiment | Mixing | 1st trial time (s) | 2nd trial time (s) | Avg time(s) | 1 | #1 and #6 | 37.56 | 33 | 35.28 | 2 | #2 and #7 | 40.54 | 38.53 | 39.535 | 3 | #3 and #8 | 51.08 | 55.79 | 53.435 | 4 | #4 and #9 | 77.00 | 73.50 | 75.25 | 5 | #5 and #10 | 203.00 | 149.19 | 176.095 | Table 3: Calculate moles of HSO3- Test tube numbers being mixed | Volume of HSO3- used | Moles of HSO3-Moles=molarity x liters | #1 and #6 | 10 mL | 0.01 L x 0.001 M = 0.00001 moles | #2 and #7 | 10 mL | 0.01 L x 0.001 M = 0.00001 moles | #3 and #8 | 10 mL | 0.01 L x 0.001 M = 0.00001 moles | #4 and #9 | 10 mL | 0.01 L x 0.001 M = 0.00001 moles | #5 and #10 | 10 mL | 0.01 L x 0.001 M = 0.00001 moles | Table 4: Calculate the rate of IO3- IO3-(aq) + 3HSO3-(aq) I-(aq) + 3SO42-(aq) + 3H+ (aq) Test tube being mixed | Moles of HSO3- | Moles of IO3- reacting | Conc. of IO3- (volume is 20 mL) | Rate of IO3- (conc./avg time) | #1 and #6 | 0.00001 | 3.33 x 10-6 | 1.67 x 10-4 | 1.67 x

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